Rami Arieli: "The Laser Adventure" Chapter 6.2.3 page 1
6.2.3 Alexandrite Laser (Cr+3:BeAl2O4)

Alexandrite laser is a solid state laser in which Chromium ions (Cr+3), at the amount of 0.01-0.4 %, are embedded in BeAl2O4 crystal.
It has energy level structure similar to the energy level structure of Ruby laser.

Alexandrite laser was operated for the first time as a three level laser in 1973 at a wavelength of 680 [nm].

A few years later, it was found that at longer wavelengths the Alexandrite laser can be operated as a four level laser, which can be tune over a range of wavelengths: 720-800 [nm].

It was the first tunable solid state laser to reach the market.

A model of energy level diagram which explain the tunability can be seen in figure 6.16.

 
Figure 6.16: Energy Level Diagram of Alexandrite Laser.