HF
The most well known member of this family is Hydrogen
Fluoride (HF).
The emitted radiation is in the Infra-Red (IR), with a few lines in
the spectrum range: 2.6 - 3.0 [mm].
DF
When Hydrogen is replaced by its heavier isotope - Deuterium,
another member of the family: Deuterium
Fluoride (DF) is created and emits in the spectrum range:
3.5 - 4.2 [mm].
Other halides such as Hydrogen Chloride (HCl) and Hydrogen Bromide (HBr) have demonstrated lasing in the lab, but are not common.
Because Fluorine and Hydrogen are very reactive gasses:
Fluorine compounds such as SF6 or NF3 are used as a source for Fluorine.
In commercial chemical lasers, Oxygen is added to the reaction chamber, to react with the Sulfur to create SO2 molecules.
Helium gas is added as a dilution gas, and sometimes other gasses as well.
The total pressure inside a chemical laser is low (a few torr).